based nitroxide and alkoxyamines species bearing a variety of substituents adjacent to the nitroxide functionality. Through variation of the nitroxide electronic structure a variation in rate of styrene polymerisation was observed and one nitroxide demonstrated the ability to mediate polymerisation of w butyl acrylate. In an attempt to rationalise this behaviour examination was carried out on model species studying the influence of nitroxide structure on thermal dissociation of alkoxyamine carbon to oxygen bond and the propensity of alkoxyamines towards hydrogen transfer disproportionation. 4MbAbstractIn this thesis I analyse the structure of scattering amplitudes in super symmetric gauge and gravitational theories in four dimensional spacetime
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