encore faut il avoir quelque chose dans la tte . The combination of living anionic polymerisation and "macromonomer" approach was successfully used for the production of both types of branched polymers demonstrating the great versatility of this synthetic methodology. HyperBlocks were constructed from well defined AB2 macromonomers of polystyrene polyisoprene polystyrene while asymmetric three arm stars involved the synthesis of well defined polystyrene arms with different chain end functionalities for the 'long' and the 'short' arm respectively. We have explored Williamson coupling reaction and copper (I) catalysed azide alkyne 'click' reaction for the final assembly of both HyperBlocks and three arm stars.
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